Research Interests

Steven Szczepankiewicz - Research Interests

Dr. Szczepankiewicz’s group is interested in developing rugged photoactivated catalysts capable of reducing small stable molecules such as CO2.

One application of reduction photocatalysis is incorporating a small inactive molecule like CO2 into some useful product.  We’ve demonstrated the ability to reduce CO2 in the presence of benzyl alcohol to produce benzyl formate, a common fragrance additive.  The reaction is completed under the following conditions:  10 µM TMS-HPT, 30 µM benzyl alcohol, 1 atm CO2, and 10 min UV (1 kW Xe).

(tha)6[SiW11O39Co(CO2)] + 2 C6H5CH2OH    



(tha)6[SiW11O39Co(__)] + C6H5CHO + C6H5CH2OOCH + H2O


We are investigating the possibility of generating H2 from ethanol using similar conditions.