Steven Szczepankiewicz - Research InterestsDr. Szczepankiewicz’s group is interested in developing rugged photoactivated catalysts capable of reducing small stable molecules such as CO
2.

One application of reduction photocatalysis is incorporating a small inactive molecule like CO
2 into some useful product. We’ve demonstrated the ability to reduce CO
2 in the presence of benzyl alcohol to produce benzyl formate, a common fragrance additive. The reaction is completed under the following conditions: 10 µM TMS-HPT, 30 µM benzyl alcohol, 1 atm CO
2, and 10 min UV (1 kW Xe).
(tha)6[SiW11O39Co(CO2)] + 2 C6H5CH2OH

(tha)
6[SiW
11O
39Co(
__)] + C
6H
5CHO + C
6H
5CH
2OOCH + H
2O
We are investigating the possibility of generating H
2 from ethanol using similar conditions.